Light-induced Electron Transfer from Tris(2,2'-bipyridine)ruthenium(II)2+ to a Nickeldithiolene in Homogeneous and Heterogeneous Systems
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چکیده
für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namensnennung 4.0 Lizenz. Light-induced Electron Transfer from Tris(2,2'-bipyridine)ruthenium(II)2+ to a Nickeldithiolene in Homogeneous and Heterogeneous Systems
منابع مشابه
Light Induced Electron Transfer Reactions of Metal Complexes
Properties of the excited states of tris(2,2'—bipyridine) and tris(l,lO—phenanthroline) complexes of chromium(III), iron(II), ruthenium(II), osmium(II), rhodium(III), and iridium(III) are described. The electron transfer reactions of the ground and excited states are discussed and interpreted in terms of the driving force for the reaction and the distortions of the excited states relative to th...
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Irradiation of 'Ru(bipy)2+ (bipy = 2,2'-bipyridine) with light below 560 nm results in the formation of a charge-transfer excited state potentially capable of reducing water to dihydrogen with concomitant production of Ru(bipy)33+. The latter may be reduced by hydroxide Ru(bipy 33+ + OH = Ru(bipy)32+ + '402 + Y/2H20 to form dioxygen and regenerate the starting complex. The use of these reaction...
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